Name: Aniline
Synonyms:
aniline; phosphoric acid;Phenylamine;Sul anilinova [Czech];Aniline sulphate (1:1);RCRA waste number U012;phenylazanium iodide;Chlorid anilinu [Czech];Anilina [Italian, Polish];Benzenamine, phosphate (1:1);NCI-C03736 hydrochloride;37832-42-1;45497-73-2;33921-12-9;Arylamine;Aminophen;2424-53-5;Benzene, amino;C.I. Oxidation Base 1;RCRA waste no. U012;C.I. 76000;Kyanol;Anilinium nitrate;Dianilinium sulphate;Benzenamine, hydrobromide;17843-02-6;NCI-C03736;phenylazanium; phosphenic acid;Anilinium bromide;BENZENE,AMINO (ANILINE);Defined Naphthalene;Anilinium hydrogen phosphite;EPA Pesticide Chemical Code 251400;Chlorhydrate daniline [French];146997-94-6;53894-37-4;benzenamine;Krystallin;CI 76000;Benzenamine, sulfate (2:1);Aniline hydrochloride (6CI,8CI);Phenylammonium chloride;Phenylamine hydrochloride;Phenyleneamine;ANILINE HYDROCHLORIDE;Aniline hydrochloride [UN1548] [Poison];Benzeneethanamine,R-methyl-;aniline; sulfuric acid;Aminobenzene;Anyvim;142-04-1;Magnesium bis(phenylamide );CI Oxidation Base 1;Benzenamine, hydrochloride;Aniline [UN1547] [Poison];Cyanol;Aniline and homologs;USAF EK-442;Huile daniline [French];542-16-5;Aniline and homologues;Anilin [Czech];542-15-4;ANILINE, HYDROGEN PHOSPHITE;Aniline oil;37342-16-8;542-11-0;aniline; nitric acid;Aniline (and salts);Blue Oil;1/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H;Benzenamine phosphate (1:1);20305-50-4;Benzidam;Aniline, Reagent;苯胺;ANILIN (CZECH);ANILINA (ITALIAN, POLISH);HUILE d′ANILINE (FRENCH);ANILINE 99+%; CAS Number:62-53-3 Molecular Formula:C6H7N Molecular Weight:93.14 EINECS:200-539-3 Density:1.0213 Boiling Point:181-185 ºC Flash Point:76 ºC Safety Description:Suspected carcinogen with experimental neoplastigenic data. A human poison by an unspecified route. Poison experimentally by most routes including inhalation and ingestion. Experimental reproductive effects. A skin and severe eye irritant, and a mild sensitizer. In the body, aniline causes formation of methemoglobin, resulting in prolonged anoxemia and depression of the central nervous system; less acute exposure causes hemolysis of the red blood cells, followed by stimulation of the bone marrow. The liver may be affected with resulting jaundice. Long-term exposure to aniline dye manufacture has been associated with malignant bladder growths. A common air contaminant. A combustible liquid when exposed to heat or flame. To fight fire, use alcohol foam, CO2, dry chemical. It can react vigorously with oxidizing materials. When heated to decomposition it emits highly toxic fumes of NOx. Spontaneously explosive reactions occur with benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, red fuming nitric acid, peroxodisulfuric acid, and tetranitromethane. Violent reactions with boron trichloride, peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloro-nitromethane (145°C), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HNO3 + N2O4 + H2SO4), (nitrobenzene + glycerin), oleum, (HCHO + HClO4), perchromates, K2O2, β-propiolactone, AgClO4, Na2O2, H2SO4, trichloromelamine, acids, peroxydisulfuric acid, FO3Cl, diisopropyl peroxy-dicarbonate, n-haloimides, and trichloronitromethane. Ignites on contact with sodium peroxide + water. Forms heat- or shock-sensitive explosive mixtures with anilinium chloride (detonates at 240°C/7.6 bar), nitromethane, hydrogen peroxide, 1-chloro-2,3-epoxypropane, and peroxomonosulfuric acid. Reactions with perchloryl fluoride, perchloric acid, and ozone form explosive products.
Analytical Methods:
For occupational chemical analysis use NIOSH: Amines, Aromatic, 2002. liansport Information:UN 1547 6.1/PG 2